I & my husband had sex & used pullout method for the first time and he came near my vagina opening it was day before my ovulation. can i get pregnant?

Yep: Take a home pregnancy test 2 weeks after the missed period. Good luck !

Not impossible: The vaginal secretions are designed to help convey swimming sperm up to the cervix and toward your fallopian tubes. If there was sperm in his pre-ejaculatory fluid, or if he released sperm near your vulva or vagina, and you were wet, then it's not impossible for you to conceive, just unlikely. I make it a rule to never say "never". Plan b is for these situations.