I'm 5 days late on my pd, i had unprotected sex on my fertile window using pull out, i'm starting to get pms now, is it possible i just ovulated late?

Possible: Teens don't always ovulate at regular times, so this is possible. However, the pull out method is horrible...absolutely horrible and a big big cause of teen pregnancy. Check a pregnancy test and stop using the pullout method. Condoms are warranted here and probably a birth control pill if you're already allowing your partner to pull out.