What is the best men's daily vitamin for general health/well being, that won't far exceed daily recommended values?

Similar. Most men's daily vitamins are similar (one a day, centrum, e.T.C). Make sure it is a men's vitamin which does not include supplemental iron, which may increase cardiovascular risk.
Any multivitamin. Any multivitamin would be good. Take it in the morning with plenty of water. Most are within recommended daily doses.
Centrum. Widely used probably the best selling one most likely half the pill does the job for most people, provided they eat salad veg fruit and fish twice weekly.