My wife is 25 years of age, our babies are 2 years and the other is 11 months. My wife is having headache pains for the last week waking up in morning?

Primary care... The first stop would be to a primary care doctor; if there is a change in the type/frequency of the headache then he/she may want to have a neurologist take a look at her. Stress can be a big factor in headaches just fyi. Good luck!