My blood report from Sunday Evening i.e. 14th june (23rd day) of 34 days cycle shows I ovulated and its 35 unit. So when did I ovulated?

Trying to clarify. Ovulation occurs about 14 days before your menstrual cycle. On a 35 day cycle you would expect ovulation on about day 21. If you had a Progesterone blood test done around day 23 with a level of 35 then this confirms you ovulated a few days before the test was done. A Progesterone level above 10 is consistent with ovulation.