Yes, it can work.
Just as Clomiphene
can stimulate the inadequately functioning ovary, it can stimulate the inadequately functioning testicle in some men.
The reason for the inadequate function is key as not every male will be able to respond. An evaluation of the male is important. The other difference is that if Clomiphene is going to work for a woman, you'll know within 2 weeks. For men, it will take 3-6 months.