I'm 5 days late on my pd, I had unprotected sex on my fertile window using pull out, I'm starting to get PMS now, is it possible I just ovulated late?

Possible. Teens don't always ovulate at regular times, so this is possible. However, the pull out method is horrible...absolutely horrible and a big big cause of teen pregnancy. Check a pregnancy test and stop using the pullout method. Condoms are warranted here and probably a birth control pill if you're already allowing your partner to pull out.