What pain killer gets rid of severe headaches tied to menstruation, PMS? Nothing works. Tried Ibuprofen, Tylenol, (acetaminophen) aspirin, naproxen atdiff. Times Ideas?

Addition of caffeine. For these types of headaches, without getting into prescription medication, and anti-inflammatory such as Ibuprofen, combined with caffeine(i.e. coffee or Mountain Dew) often helps. An ice pack 15 to 20 minutes at a time is also helpful as is stretching affected neck, etc. muscles.
Menstrual migraines. See a neurologist. triptans or Fioricet (acetaminophen butalbital and caffeine) may work. If frequency is more than 4 days a month then prophylactic medications will help.