Please help! What is the most comfortable toe splint you can get for correcting toe alignment after surgery?

Comfort. Is dependent on the person wearing it. What works well for one may not for another. Are you referring to hammertoe surgery? Or bunion surgery? If bunions, darco makes a nice product called the great toe splint. For hammertoes, I usually bandage with coban for the patients for first 4 weeks, by then, they copy my technique if they want to continue strapping.